Overview of recycling gold and silver from waste materials

The work of recycling gold and silver from waste raw materials has received widespread attention from countries around the world in recent decades. Take the United States as an example. In the early 1980s, there were more than 1,200 companies engaged in the recovery of precious metals such as gold and silver. In 1974, 2,400 tons of regenerated silver was recovered from waste materials, which was 2.28 times that of minerals in that year. Recycled gold is 80.6t, accounting for 5% of the annual gold production. In 1978, 5,660 tons of silver was recovered from scrap and currency, ranking first in the world. There are more than 150 companies that recycle silver from photo-based waste in Japan, and 300-400 tons of silver is recycled every year. In order to reclaim precious metals from used raw materials, Johnson Matthey invested more than $14 million to convert the gold refinery in Brinsdown, England, into a precious metal recycling facility for waste materials in 1977. plant. The plant was commissioned in October 1979. It is the world's largest waste raw material processing plant and the processing center for waste precious metals in the Western world.

Recovering gold and silver from waste raw materials, due to the wide range of raw materials, complex types, and disparity in grades (from tens of percent to 90% or more), in order to reduce processing and reduce production costs, the primary problem Different raw materials are classified according to the shape, type and grade of the materials, so that different treatment methods can be selected according to different raw materials. The main types of gold, silver, and gold and silver-containing waste materials and important treatment methods are summarized in Tables 1 and 2.

Table 1 Types of major silver and silver-containing waste materials and important treatment methods

species

Approach

species

Approach

X-ray and photo film impression paper

Incineration method

currency

jewelry

Casting and processing debris

Package (overlay) silver metal or alloy

Silver plated metal products

Silver battery

Silver battery

Electrolysis

2. Acid dissolution

Film, TV copy film factory

Scrap

2. Dissolution method

Electrical switch contact

Electrolysis

Silver solder

2. Acid dissolution

Telephone exchange device

3. Slag smelting

Integrated circuit board

After incineration (or drying)

Silver chloride

Silver iodide

Silver bromide

Silver manganese

Protein silver

1. Add zinc and iron to the acid solution

2. Co-melting with soda

3. Ammonia or dimethyl sulfoxide dissolved

A printed circuit board

Acid or fire enrichment

Electrical appliances, resistance paste

Mirror waste cotton

Silver sulfide

1. Smelting with soda and iron filings

2. After the nitric acid is dissolved

Electrolysis or precipitation

Mirror waste

Thermos

Acid dissolution

2. Mechanical brushing

Fixer

Film factory waste emulsion

Plating solution

Silver-containing wastewater

Silver wash water

Chemical precipitation

2. Electrolysis

3. Replacement

4. Activated carbon adsorption

5. Ion exchange

6. Solvent extraction

Waste silver nitrate

Recrystallization

2. Electrolysis

3. Copper or zinc replacement

4. Chloride ion precipitation

Silver catalyst

Alkali precipitation after acid dissolution

Silver-containing garbage

Flotation

Slag, demolition,

Silver smelting

2. After the crushing and screening, the fire method

Table 2 Types of major gold and gold-containing waste materials and important treatment methods

species

Approach

species

Approach

Jewelry, decorations

1. Fire enrichment

Platinum rhodium thermocouple wire

1. Fire enrichment

currency

Gold platinum spinneret

Casting and processing debris, burrs, plating residues and scrap

2. Chlorination smelting

Iridium nib

2. Separation and purification after dissolving aqua regia

Gold-plated electronic components, devices

3. Liquid chlorination replacement

Gold, platinum, palladium , rhodium alloy

SCR contacts, base plates,

Dental sleeves, alloys and plates, coated (overlay) gold metal and

Alloy, gold nib

4. Basket anodic electrolysis

Gold-containing silicon electronic components

1. Fire enrichment

2. Silicon etchant in addition to silicon

Gold-plated integrated circuit board

Fire enrichment or wet leaching after incineration

Alchemy

Refractory lining

Optical metal glass

Cermet

Resistance, capacitor

Classification and smelting after crushing and screening

Gold-plated printed circuit board

Gold couplet

Gold signboard

Dental plastic

Cyanide solution

1. Zinc, copper replacement (or ferrous reduction)

Chlorinated solution

2. Activated carbon adsorption

Electroplated anode mud

Fire enrichment or

Wet leaching

Wang Shui Liquid

3. Ion exchange

Various wash water

4. Solvent extraction

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