Hefei Institute of Chinese Academy of Sciences: progress in heavy metal ion detection research

[China Instrument Network Instrument Development] Soil heavy metal pollution is harmful to human health, and it has important scientific significance to detect and analyze heavy metal ions in soil. Recently, Xiong Shiquan, a researcher at the Institute of Technology Biology and Agricultural Engineering of the Chinese Academy of Sciences' Hefei Institute of Physical Science, constructed electrode materials by irradiating clay-ionic liquid complexes to achieve Cd(II), Pb(II), and Hg(II). Cu (II) detection and interaction analysis.


Determination of Pb(II), Cd(II), Hg(II) and Cu(II) by irradiated attapulgite-ionic liquid complexes
In the electrochemical detection of heavy metal ions, most researches use higher cost synthetic materials to construct electrodes, measure one or more ions and study their mechanism. In this study, the research group used irradiated, inexpensive natural materials and ionic liquids with good conductivity to form complexes, enabling the detection and analysis of multiple heavy ions, and determining the differences in sensitivity and detection limits.

The researchers first used high-energy electron beams to irradiate attapulgite. By optimizing the irradiation parameters and a series of characterizations, the attapulgite-ionic liquid composite was used to construct the electrode materials. At the same time, Pb(II), Cd(II), and Hg were used. (II) and Cu(II) were separately and simultaneously electrochemically detected. The dissolution behavior was analyzed and compared. It was found that the sensitivity and detection limit of the two assays were changed to different degrees. In the simultaneous detection, the detection limit and sensitivity of the composite materials on Hg(II) and Cu(II) were significantly improved, while the detection effect on Pb(II) and Cd(II) was reduced, among which Pb( The detection limits of II), Cd(II), Cu(II), and Hg(II) were 0.8, 0.5, 0.2, and 0.06 nM, respectively, while the sensitivity to Hg(II) was as high as 242.4 μA/μM.

The work has a certain reference value for the study of a variety of heavy metal ions and the detection of heavy metals in actual soil, and also provides a reference for the detection and analysis of a variety of heavy metal ions. The relevant research results were published in Chemical Engineering Journal 316 (2017) 383–392. The above research work was supported by the National Natural Science Foundation of China and the Institute of Technology Biology.

(Original title: Hefei Research Institute made progress in detection and analysis of heavy metal ions)

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